04. Conductance and Conductor
ELECTROCHEMISTRY

276225 Assertion : If $\lambda_{\mathrm{Na}^{+}}^{\circ}$ and $\lambda_{\mathrm{Cr}}^{\circ}$ are molar limiting conductivity of sodium and chloride ions respectively, then the limiting molar conductivity for sodium chloride is given by the equation:
$\lambda_{\mathrm{NaCl}}^{\circ}=\lambda_{\mathrm{Na}}^{\circ}+\lambda_{\mathrm{Cr}}^{\circ}$
Reason : This is according to Kohlrausch law of independent migration of ions.

1 If both Assertion and Reason are correct and the Reason is the correct explanation of Assertion.
2 If both Assertion and Reason are correct, but Reason is not the correct explanation of Assertion.
3 If Assertion is correct but Reason is in correct.
4 If both the Assertion and Reason are incorrect.
ELECTROCHEMISTRY

276159 The aqueous solution of which of the following complex has the least conductivity under identical conditions.

1 Penta aqua chlorido chromium (III) chloride
2 Tetra aqua dichlorido chromium (III) chloride
3 Hexa aqua chromium (III) chloride
4 Tri aqua trichlorido chromium (III)
ELECTROCHEMISTRY

276202 | Electrolyte | $\mathrm{KCl}$ | $\mathrm{KNO}_3$ | $\mathrm{HCl}$ | $\mathrm{NaOAc}$ | $\mathrm{NaCl}$ |
| :--- | :--- | :--- | :--- | :--- | :--- |
| $\Lambda^{\infty}(\mathrm{S}$ | 149.9 | 145.0 | 426.2 | 91.0 | 126.5 |
| $\left.\mathrm{~cm}^2 \mathrm{~mol}^{-1}\right)$ | | | | | |

1 217.5
2 390.7
3 552.7
4 517.2
ELECTROCHEMISTRY

276215 Which of the following complexes has lowest molar conductance?

1 $\mathrm{CoCl}_{3} .3 \mathrm{NH}_{3}$
2 $\mathrm{CoCl}_{3} .4 \mathrm{NH}_{3}$
3 $\mathrm{CoCl}_{3} .5 \mathrm{NH}_{3}$
4 $\mathrm{CoCl}_{3} \cdot 6 \mathrm{NH}_{3}$
ELECTROCHEMISTRY

276225 Assertion : If $\lambda_{\mathrm{Na}^{+}}^{\circ}$ and $\lambda_{\mathrm{Cr}}^{\circ}$ are molar limiting conductivity of sodium and chloride ions respectively, then the limiting molar conductivity for sodium chloride is given by the equation:
$\lambda_{\mathrm{NaCl}}^{\circ}=\lambda_{\mathrm{Na}}^{\circ}+\lambda_{\mathrm{Cr}}^{\circ}$
Reason : This is according to Kohlrausch law of independent migration of ions.

1 If both Assertion and Reason are correct and the Reason is the correct explanation of Assertion.
2 If both Assertion and Reason are correct, but Reason is not the correct explanation of Assertion.
3 If Assertion is correct but Reason is in correct.
4 If both the Assertion and Reason are incorrect.
ELECTROCHEMISTRY

276159 The aqueous solution of which of the following complex has the least conductivity under identical conditions.

1 Penta aqua chlorido chromium (III) chloride
2 Tetra aqua dichlorido chromium (III) chloride
3 Hexa aqua chromium (III) chloride
4 Tri aqua trichlorido chromium (III)
ELECTROCHEMISTRY

276202 | Electrolyte | $\mathrm{KCl}$ | $\mathrm{KNO}_3$ | $\mathrm{HCl}$ | $\mathrm{NaOAc}$ | $\mathrm{NaCl}$ |
| :--- | :--- | :--- | :--- | :--- | :--- |
| $\Lambda^{\infty}(\mathrm{S}$ | 149.9 | 145.0 | 426.2 | 91.0 | 126.5 |
| $\left.\mathrm{~cm}^2 \mathrm{~mol}^{-1}\right)$ | | | | | |

1 217.5
2 390.7
3 552.7
4 517.2
ELECTROCHEMISTRY

276215 Which of the following complexes has lowest molar conductance?

1 $\mathrm{CoCl}_{3} .3 \mathrm{NH}_{3}$
2 $\mathrm{CoCl}_{3} .4 \mathrm{NH}_{3}$
3 $\mathrm{CoCl}_{3} .5 \mathrm{NH}_{3}$
4 $\mathrm{CoCl}_{3} \cdot 6 \mathrm{NH}_{3}$
ELECTROCHEMISTRY

276225 Assertion : If $\lambda_{\mathrm{Na}^{+}}^{\circ}$ and $\lambda_{\mathrm{Cr}}^{\circ}$ are molar limiting conductivity of sodium and chloride ions respectively, then the limiting molar conductivity for sodium chloride is given by the equation:
$\lambda_{\mathrm{NaCl}}^{\circ}=\lambda_{\mathrm{Na}}^{\circ}+\lambda_{\mathrm{Cr}}^{\circ}$
Reason : This is according to Kohlrausch law of independent migration of ions.

1 If both Assertion and Reason are correct and the Reason is the correct explanation of Assertion.
2 If both Assertion and Reason are correct, but Reason is not the correct explanation of Assertion.
3 If Assertion is correct but Reason is in correct.
4 If both the Assertion and Reason are incorrect.
ELECTROCHEMISTRY

276159 The aqueous solution of which of the following complex has the least conductivity under identical conditions.

1 Penta aqua chlorido chromium (III) chloride
2 Tetra aqua dichlorido chromium (III) chloride
3 Hexa aqua chromium (III) chloride
4 Tri aqua trichlorido chromium (III)
ELECTROCHEMISTRY

276202 | Electrolyte | $\mathrm{KCl}$ | $\mathrm{KNO}_3$ | $\mathrm{HCl}$ | $\mathrm{NaOAc}$ | $\mathrm{NaCl}$ |
| :--- | :--- | :--- | :--- | :--- | :--- |
| $\Lambda^{\infty}(\mathrm{S}$ | 149.9 | 145.0 | 426.2 | 91.0 | 126.5 |
| $\left.\mathrm{~cm}^2 \mathrm{~mol}^{-1}\right)$ | | | | | |

1 217.5
2 390.7
3 552.7
4 517.2
ELECTROCHEMISTRY

276215 Which of the following complexes has lowest molar conductance?

1 $\mathrm{CoCl}_{3} .3 \mathrm{NH}_{3}$
2 $\mathrm{CoCl}_{3} .4 \mathrm{NH}_{3}$
3 $\mathrm{CoCl}_{3} .5 \mathrm{NH}_{3}$
4 $\mathrm{CoCl}_{3} \cdot 6 \mathrm{NH}_{3}$
ELECTROCHEMISTRY

276225 Assertion : If $\lambda_{\mathrm{Na}^{+}}^{\circ}$ and $\lambda_{\mathrm{Cr}}^{\circ}$ are molar limiting conductivity of sodium and chloride ions respectively, then the limiting molar conductivity for sodium chloride is given by the equation:
$\lambda_{\mathrm{NaCl}}^{\circ}=\lambda_{\mathrm{Na}}^{\circ}+\lambda_{\mathrm{Cr}}^{\circ}$
Reason : This is according to Kohlrausch law of independent migration of ions.

1 If both Assertion and Reason are correct and the Reason is the correct explanation of Assertion.
2 If both Assertion and Reason are correct, but Reason is not the correct explanation of Assertion.
3 If Assertion is correct but Reason is in correct.
4 If both the Assertion and Reason are incorrect.
ELECTROCHEMISTRY

276159 The aqueous solution of which of the following complex has the least conductivity under identical conditions.

1 Penta aqua chlorido chromium (III) chloride
2 Tetra aqua dichlorido chromium (III) chloride
3 Hexa aqua chromium (III) chloride
4 Tri aqua trichlorido chromium (III)
ELECTROCHEMISTRY

276202 | Electrolyte | $\mathrm{KCl}$ | $\mathrm{KNO}_3$ | $\mathrm{HCl}$ | $\mathrm{NaOAc}$ | $\mathrm{NaCl}$ |
| :--- | :--- | :--- | :--- | :--- | :--- |
| $\Lambda^{\infty}(\mathrm{S}$ | 149.9 | 145.0 | 426.2 | 91.0 | 126.5 |
| $\left.\mathrm{~cm}^2 \mathrm{~mol}^{-1}\right)$ | | | | | |

1 217.5
2 390.7
3 552.7
4 517.2
ELECTROCHEMISTRY

276215 Which of the following complexes has lowest molar conductance?

1 $\mathrm{CoCl}_{3} .3 \mathrm{NH}_{3}$
2 $\mathrm{CoCl}_{3} .4 \mathrm{NH}_{3}$
3 $\mathrm{CoCl}_{3} .5 \mathrm{NH}_{3}$
4 $\mathrm{CoCl}_{3} \cdot 6 \mathrm{NH}_{3}$