04. Bond Energy
Thermodynamics

273048 If the bond energies of $\mathrm{H}-\mathrm{H}, \mathrm{Br}-\mathrm{Br}$, and $\mathrm{H}-$ $B r$ are 433,192 and $364 \mathrm{~kJ} \mathrm{~mol}^{-1}$ respectively, the $\Delta \mathrm{H}^0$ for the reaction $\mathrm{H}_2(\mathrm{~g})+\mathrm{Br}_2(\mathrm{~g}) \rightarrow$ $2 \mathrm{HBr}(\mathrm{g})$ is

1 $-261 \mathrm{~kJ}$
2 $+103 \mathrm{~kJ}$
3 $+261 \mathrm{~kJ}$
4 $-103 \mathrm{~kJ}$
Thermodynamics

273049 Given that bond energies of \(\mathrm{H}-\mathrm{H}\) and \(\mathrm{Cl}-\mathrm{Cl}\) are \(430 \mathrm{~kJ} \mathrm{~mol}^{-1}\) and \(240 \mathrm{~kJ} \mathrm{~mol}^{-1}\) respectively and \(\Delta \mathrm{H}_{\mathrm{f}}\) for \(\mathrm{HCl}\) is \(-90 \mathrm{~kJ} \mathrm{~mol}^{-1}\), bond enthalpy of \(\mathrm{HCl}\) is

1 \(380 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
2 \(425 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
3 \(245 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
4 \(290 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
Thermodynamics

273050 For the reaction
$\mathbf{A}(\mathrm{g})+2 \mathbf{B}(\mathrm{g}) \longrightarrow 2 \mathbf{C}(\mathrm{g})-\mathbf{3 D}(\mathrm{g})$
the change of enthalpy at $27^{\circ} \mathrm{C}$ is 19 kcal. The value of $\Delta E$ is: $\left(R=2.02 \mathrm{cal} \mathrm{K}^{-1} \mathrm{~mol}^{-1}\right)$

1 $21.2 \mathrm{kcal}$
2 $17.8 \mathrm{kcal}$
3 $18.4 \mathrm{kcal}$
4 $20.6 \mathrm{kcal}$
Thermodynamics

273037 At $298 \mathrm{~K}$ temperature the activation energy for the reaction $x_2+y_2 \rightarrow 2 x y+20 k J$ is $15 \mathrm{~kJ}$.
What will be the activation energy for the reaction $2 x y \rightarrow x_2+y_2$ ?

1 $-15 \mathrm{~kJ}$
2 $+35 \mathrm{~kJ}$
3 $-5 \mathrm{~kJ}$
4 $-35 \mathrm{~kJ}$
Thermodynamics

273048 If the bond energies of $\mathrm{H}-\mathrm{H}, \mathrm{Br}-\mathrm{Br}$, and $\mathrm{H}-$ $B r$ are 433,192 and $364 \mathrm{~kJ} \mathrm{~mol}^{-1}$ respectively, the $\Delta \mathrm{H}^0$ for the reaction $\mathrm{H}_2(\mathrm{~g})+\mathrm{Br}_2(\mathrm{~g}) \rightarrow$ $2 \mathrm{HBr}(\mathrm{g})$ is

1 $-261 \mathrm{~kJ}$
2 $+103 \mathrm{~kJ}$
3 $+261 \mathrm{~kJ}$
4 $-103 \mathrm{~kJ}$
Thermodynamics

273049 Given that bond energies of \(\mathrm{H}-\mathrm{H}\) and \(\mathrm{Cl}-\mathrm{Cl}\) are \(430 \mathrm{~kJ} \mathrm{~mol}^{-1}\) and \(240 \mathrm{~kJ} \mathrm{~mol}^{-1}\) respectively and \(\Delta \mathrm{H}_{\mathrm{f}}\) for \(\mathrm{HCl}\) is \(-90 \mathrm{~kJ} \mathrm{~mol}^{-1}\), bond enthalpy of \(\mathrm{HCl}\) is

1 \(380 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
2 \(425 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
3 \(245 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
4 \(290 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
Thermodynamics

273050 For the reaction
$\mathbf{A}(\mathrm{g})+2 \mathbf{B}(\mathrm{g}) \longrightarrow 2 \mathbf{C}(\mathrm{g})-\mathbf{3 D}(\mathrm{g})$
the change of enthalpy at $27^{\circ} \mathrm{C}$ is 19 kcal. The value of $\Delta E$ is: $\left(R=2.02 \mathrm{cal} \mathrm{K}^{-1} \mathrm{~mol}^{-1}\right)$

1 $21.2 \mathrm{kcal}$
2 $17.8 \mathrm{kcal}$
3 $18.4 \mathrm{kcal}$
4 $20.6 \mathrm{kcal}$
Thermodynamics

273037 At $298 \mathrm{~K}$ temperature the activation energy for the reaction $x_2+y_2 \rightarrow 2 x y+20 k J$ is $15 \mathrm{~kJ}$.
What will be the activation energy for the reaction $2 x y \rightarrow x_2+y_2$ ?

1 $-15 \mathrm{~kJ}$
2 $+35 \mathrm{~kJ}$
3 $-5 \mathrm{~kJ}$
4 $-35 \mathrm{~kJ}$
Thermodynamics

273048 If the bond energies of $\mathrm{H}-\mathrm{H}, \mathrm{Br}-\mathrm{Br}$, and $\mathrm{H}-$ $B r$ are 433,192 and $364 \mathrm{~kJ} \mathrm{~mol}^{-1}$ respectively, the $\Delta \mathrm{H}^0$ for the reaction $\mathrm{H}_2(\mathrm{~g})+\mathrm{Br}_2(\mathrm{~g}) \rightarrow$ $2 \mathrm{HBr}(\mathrm{g})$ is

1 $-261 \mathrm{~kJ}$
2 $+103 \mathrm{~kJ}$
3 $+261 \mathrm{~kJ}$
4 $-103 \mathrm{~kJ}$
Thermodynamics

273049 Given that bond energies of \(\mathrm{H}-\mathrm{H}\) and \(\mathrm{Cl}-\mathrm{Cl}\) are \(430 \mathrm{~kJ} \mathrm{~mol}^{-1}\) and \(240 \mathrm{~kJ} \mathrm{~mol}^{-1}\) respectively and \(\Delta \mathrm{H}_{\mathrm{f}}\) for \(\mathrm{HCl}\) is \(-90 \mathrm{~kJ} \mathrm{~mol}^{-1}\), bond enthalpy of \(\mathrm{HCl}\) is

1 \(380 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
2 \(425 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
3 \(245 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
4 \(290 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
Thermodynamics

273050 For the reaction
$\mathbf{A}(\mathrm{g})+2 \mathbf{B}(\mathrm{g}) \longrightarrow 2 \mathbf{C}(\mathrm{g})-\mathbf{3 D}(\mathrm{g})$
the change of enthalpy at $27^{\circ} \mathrm{C}$ is 19 kcal. The value of $\Delta E$ is: $\left(R=2.02 \mathrm{cal} \mathrm{K}^{-1} \mathrm{~mol}^{-1}\right)$

1 $21.2 \mathrm{kcal}$
2 $17.8 \mathrm{kcal}$
3 $18.4 \mathrm{kcal}$
4 $20.6 \mathrm{kcal}$
Thermodynamics

273037 At $298 \mathrm{~K}$ temperature the activation energy for the reaction $x_2+y_2 \rightarrow 2 x y+20 k J$ is $15 \mathrm{~kJ}$.
What will be the activation energy for the reaction $2 x y \rightarrow x_2+y_2$ ?

1 $-15 \mathrm{~kJ}$
2 $+35 \mathrm{~kJ}$
3 $-5 \mathrm{~kJ}$
4 $-35 \mathrm{~kJ}$
Thermodynamics

273048 If the bond energies of $\mathrm{H}-\mathrm{H}, \mathrm{Br}-\mathrm{Br}$, and $\mathrm{H}-$ $B r$ are 433,192 and $364 \mathrm{~kJ} \mathrm{~mol}^{-1}$ respectively, the $\Delta \mathrm{H}^0$ for the reaction $\mathrm{H}_2(\mathrm{~g})+\mathrm{Br}_2(\mathrm{~g}) \rightarrow$ $2 \mathrm{HBr}(\mathrm{g})$ is

1 $-261 \mathrm{~kJ}$
2 $+103 \mathrm{~kJ}$
3 $+261 \mathrm{~kJ}$
4 $-103 \mathrm{~kJ}$
Thermodynamics

273049 Given that bond energies of \(\mathrm{H}-\mathrm{H}\) and \(\mathrm{Cl}-\mathrm{Cl}\) are \(430 \mathrm{~kJ} \mathrm{~mol}^{-1}\) and \(240 \mathrm{~kJ} \mathrm{~mol}^{-1}\) respectively and \(\Delta \mathrm{H}_{\mathrm{f}}\) for \(\mathrm{HCl}\) is \(-90 \mathrm{~kJ} \mathrm{~mol}^{-1}\), bond enthalpy of \(\mathrm{HCl}\) is

1 \(380 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
2 \(425 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
3 \(245 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
4 \(290 \mathrm{~kJ} \mathrm{~mol}^{-1}\)
Thermodynamics

273050 For the reaction
$\mathbf{A}(\mathrm{g})+2 \mathbf{B}(\mathrm{g}) \longrightarrow 2 \mathbf{C}(\mathrm{g})-\mathbf{3 D}(\mathrm{g})$
the change of enthalpy at $27^{\circ} \mathrm{C}$ is 19 kcal. The value of $\Delta E$ is: $\left(R=2.02 \mathrm{cal} \mathrm{K}^{-1} \mathrm{~mol}^{-1}\right)$

1 $21.2 \mathrm{kcal}$
2 $17.8 \mathrm{kcal}$
3 $18.4 \mathrm{kcal}$
4 $20.6 \mathrm{kcal}$
Thermodynamics

273037 At $298 \mathrm{~K}$ temperature the activation energy for the reaction $x_2+y_2 \rightarrow 2 x y+20 k J$ is $15 \mathrm{~kJ}$.
What will be the activation energy for the reaction $2 x y \rightarrow x_2+y_2$ ?

1 $-15 \mathrm{~kJ}$
2 $+35 \mathrm{~kJ}$
3 $-5 \mathrm{~kJ}$
4 $-35 \mathrm{~kJ}$